Репост из: JACS ASAP
Balancing N2 Activation in Two-Dimensional Electrides for Ammonia Synthesis
Ruoqian Jiang, Seungmin Yu, Fangkun Sun, Miao Xu, Xiaojun Lu, Zichuang Li, Wen-Qian Li, Kailong Qian, Sijia Zheng, Jiaqi Wang, Yanpeng Qi, Jun Li, Linfeng Pan, Sang-Won Park*, Jiazhen Wu*, Jie-Sheng Chen, Tian-Nan Ye*
Abstract: Two-dimensional (2D) electrides, featuring interlayer-delocalized anionic electrons, hold promise for N2 activation but face challenges in catalytic ammonia synthesis due to structural instability under reaction conditions. Here, we introduce a dual-site catalyst using the robust 2D metal carbide Y2C electride as a platform, where N2 is activated at electron-rich interlayers and H2 dissociates on supported Ni nanoparticles, enabling efficient and stable ammonia production. Through Raman spectroscopy, XPS, and DFT calculations, we uncover a scaling relationship for N2 activation in 2D electrides: intermediate N2 binding strength correlates with the formation of reactive (N2)δ− intermediates, crucial for efficient NH3 production. Leveraging this insight, La-doped Y2C (La-Y2C) optimizes N2 activation, and the Ni/La-Y2C catalyst achieves an exceptional activity of 34.6 mmol·g–1·h–1 at 400 °C and 1.0 MPa, surpassing reported Ni-based catalysts, the benchmark Cs–Ru/MgO, and industrial wüstite-based Fe under identical conditions. These findings provide a rational framework for designing advanced 2D electrides for controllable N2 activation and sustainable ammonia synthesis.
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Ruoqian Jiang, Seungmin Yu, Fangkun Sun, Miao Xu, Xiaojun Lu, Zichuang Li, Wen-Qian Li, Kailong Qian, Sijia Zheng, Jiaqi Wang, Yanpeng Qi, Jun Li, Linfeng Pan, Sang-Won Park*, Jiazhen Wu*, Jie-Sheng Chen, Tian-Nan Ye*
Abstract: Two-dimensional (2D) electrides, featuring interlayer-delocalized anionic electrons, hold promise for N2 activation but face challenges in catalytic ammonia synthesis due to structural instability under reaction conditions. Here, we introduce a dual-site catalyst using the robust 2D metal carbide Y2C electride as a platform, where N2 is activated at electron-rich interlayers and H2 dissociates on supported Ni nanoparticles, enabling efficient and stable ammonia production. Through Raman spectroscopy, XPS, and DFT calculations, we uncover a scaling relationship for N2 activation in 2D electrides: intermediate N2 binding strength correlates with the formation of reactive (N2)δ− intermediates, crucial for efficient NH3 production. Leveraging this insight, La-doped Y2C (La-Y2C) optimizes N2 activation, and the Ni/La-Y2C catalyst achieves an exceptional activity of 34.6 mmol·g–1·h–1 at 400 °C and 1.0 MPa, surpassing reported Ni-based catalysts, the benchmark Cs–Ru/MgO, and industrial wüstite-based Fe under identical conditions. These findings provide a rational framework for designing advanced 2D electrides for controllable N2 activation and sustainable ammonia synthesis.
❯ Link to the article